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H26072 3-Pyrroline, tech. 85% (remainder pyrrolidine)

CAS Number
109-96-6
Synonyms

Stock No. Size Price ($) Quantity Availability
H26072-03 1g 40.40
H26072-06 5g 134.00
H26072-14 25g 427.00
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3-Pyrroline, tech. 85% (remainder pyrrolidine)

MDL
MFCD00005213
EINECS
203-723-1

Chemical Properties

Formula
C4H7N
Formula Weight
69.11
Boiling Point
90-91°
Flash Point
-18°(0°F)
Density
0.902
Refractive Index
1.4690
Storage & Sensitivity
Keep Cold. Hygroscopic. Air Sensitive. Store under Argon.
Solubility
Soluble in alcohol and ether. Miscible with water.

Applications

3-Pyrroline is suitable to the core-level binding energies of simple unsaturated organic molecules bonded to the Si(001) surface by X-ray photoelectron spectroscopy (XPS). It is used in the synthesis of renin inhibitors and vasodilators.

Notes

Air sensitive. Store at -20°C. Store away from oxidizing agents, air.

Literature References

Martin P. Green; Jeremy C. Prodger; Alexandra E. Sherlock and Christopher J. Hayes. A Convenient Method for 3-Pyrroline Synthesis. Org. Lett. 2001, 3 (21), 1-4.

Masahiro Sai and Seijiro Matsubara. Silver-Catalyzed Intramolecular Chloroamination of Allenes: Easy Access to Functionalized 3-Pyrroline and Pyrrole Derivatives. Org. Lett. 2011, 13 (17), 4676-4679.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314

Highly flammable liquid and vapour. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,8017
Beilstein
103173
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2933.99
TSCA
Yes

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