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2',4',6'-Trifluoroacetophenone was the reactant in the synthesis of 4, 6-and 6, 7-difluoro-3-methyl-1H-indazoles.
Carlos Pérez Medina,; Concepción López,; Rosa M. Claramunt,; José Elguero.Synthesis, reactivity, and NMR spectroscopy of 4,6- and 6,7-difluoro-3-methyl-1H-indazoles Journal of Heterocyclic Chemistry. 2009, 46 (6), 1408-1412.
Krishna C. Joshi,; Vijai N. Pathak,; Vineeta GroverMiss. Studies in fluorinated 1,3-diketones and related compounds Part XII. Synthesis and spectroscopic studies of some new polyfluorinated 1,3-diketones, and their copper 1,3-diketonates. Journal of Fluorine Chemistry. 1981, 17(6),555-560.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant