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H26223 tert-Butyl hydrogen malonate, 96%

CAS Number
40052-13-9
Synonyms
mono-tert-Butyl malonate
Malonic acid mono-tert butyl ester

Stock No. Size Price ($) Quantity Availability
H26223-06 5g 43.10
H26223-14 25g 168.00
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tert-Butyl hydrogen malonate, 96%

MDL
MFCD00191886

Chemical Properties

Formula
C7H12O4
Formula Weight
160.17
Melting point
19-20°
Boiling Point
90°/2mm
Flash Point
91°(195°F)
Density
1.04
Refractive Index
1.426
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in ethanol.

Applications

tert-Butyl hydrogen malonate may be used in the preparation of dendritic precursor to asymmetric methanofullerenes, hapten-3,6-(O,S-dimethylthiophosphoramido)-6-oxohexanoic acid, hapten-4,3-(O,S-dimethylthiophosphoramido)-3-oxopropanoic acid.

Notes

Store in a cool, dry condition in a well sealed container.

Literature References

Jae Koo Lee; Ki Chang Ahn; Donald W Stoutamire; Shirley J Gee; Bruce D Hammock. Development of an enzyme-linked immunosorbent assay for the detection of the organophosphorus insecticide acephate. Journal of Agricultural and Food Chemistry. 2003, 51 (13), 3695-3703.

Helen S Toogood; Edward J Hollingsworth; Rob C Brown; Ian N Taylor; Stephen J C Taylor; Ray McCague; Jennifer A Littlechild. A thermostable L-aminoacylase from Thermococcus litoralis: cloning, overexpression, characterization, and applications in biotransformations. The Journal of Chemical Thermodynamics. 2002, 6 (2), 111-122.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H314-H330-H335

Combustible liquid. Causes severe skin burns and eye damage. Fatal if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P235-P260-P264b-P271-P280-P284-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1765457
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2917.19
TSCA
No

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