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23719-80-4 - Cyclopropylmagnesium bromide, 0.5M-0.7M in THF - H26273 - Alfa Aesar

H26273 Cyclopropylmagnesium bromide, 0.5M-0.7M in THF

CAS Number
23719-80-4
Synonyms

Size Price ($) Quantity Availability
25ml 78.40
100ml 210.00
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Cyclopropylmagnesium bromide, 0.5M-0.7M in THF

MDL
MFCD00672094

Chemical Properties

Formula
C3H5BrMg
Formula Weight
145.28
Flash Point
-17°(1°F)
Density
0.968
Sensitivity
Air & Moisture Sensitive
Solubility
Soluble in water (17 mg/ml), (25°C). Soluble in organic solvents.

Applications

It often acts as the starting nutrient mix for dropout studies where fermentation conditions required the absence of one or more essential amino acids. For classifying Yeasts based on colonial characteristics and cell morphology.

Notes

Air & Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, air, water and moisture.

Literature References

H. M. Walborsky,; Christoph Zimmermann.The surface nature of Grignard reagent formation. Cyclopropylmagnesium bromide. J. Am. Chem. Soc. 1992, 114 (13), 4996-5000.

Chutian Shu,; Kanwar Sidhu,; Li Zhang,; Xiao-jun Wang,; Dhileepkumar Krishnamurthy,; Chris H. Senanayake.Palladium-Catalyzed Cross-Coupling of Cyclopropylmagnesium Bromide with Aryl Bromides Mediated by Zinc Halide Additives . J. Org. Chem. 2010 , 74(19), 6677-6680.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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