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H26345 1-Phenylethyl mercaptan, 98%

CAS Number
6263-65-6
Synonyms
alpha-Methylbenzyl mercaptan

Stock No. Size Price ($) Quantity Availability
H26345-03 1g 37.80
H26345-09 10g 196.00
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1-Phenylethyl mercaptan, 98%

MDL
MFCD00053515

Chemical Properties

Formula
C8H10S
Formula Weight
138.23
Flash Point
76°(169°F)
Density
1.021
Refractive Index
1.5580
Storage & Sensitivity
Keep Cold. Air Sensitive. Store under Argon.
Solubility
Insoluble in water. Solubility in ethanol.

Applications

The compound is used as a source of the thiol functional group in organic synthesis. It is introduced by S-alkylation to give alkyl benzylthioethers.

Notes

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, air.

Literature References

E.J. Corey,; Karlene A. Cimprich. Enantioselective routes to chiral benzylic thiols, sulfinic esters and sulfonic acids illustrated by the 1-phenylethyl series. Tetrahedron Letters. 1992, 33 (29), 4099-4102.

László Garamszegia,; Christian Donzela,; Géraldine Carrotb,; Tuan Q. Nguyena,; Jöns Hilbornc. Synthesis of thiol end-functional polystyrene via atom transfer radical polymerization. Reactive and Functional Polymers. 2003, 55 (2),179-183.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302+H312+H332-H315-H319-H335

Combustible liquid. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2930.90
TSCA
Yes

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