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6263-65-6 - 1-Phenylethyl mercaptan, 98% - alpha-Methylbenzyl mercaptan - H26345 - Alfa Aesar

H26345 1-Phenylethyl mercaptan, 98%

CAS Number
6263-65-6
Synonyms
alpha-Methylbenzyl mercaptan

Size Price ($) Quantity Availability
1g 36.67
10g 189.52
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1-Phenylethyl mercaptan, 98%

MDL
MFCD00053515

Chemical Properties

Formula
C8H10S
Formula Weight
138.23
Flash Point
76°(169°F)
Density
1.021
Refractive Index
1.5580
Sensitivity
Air Sensitive
Solubility
Insoluble in water. Solubility in ethanol.

Applications

The compound is used as a source of the thiol functional group in organic synthesis. It is introduced by S-alkylation to give alkyl benzylthioethers.

Notes

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, air.

Literature References

E.J. Corey,; Karlene A. Cimprich. Enantioselective routes to chiral benzylic thiols, sulfinic esters and sulfonic acids illustrated by the 1-phenylethyl series. Tetrahedron Letters. 1992, 33 (29), 4099-4102.

László Garamszegia,; Christian Donzela,; Géraldine Carrotb,; Tuan Q. Nguyena,; Jöns Hilbornc. Synthesis of thiol end-functional polystyrene via atom transfer radical polymerization. Reactive and Functional Polymers. 2003, 55 (2),179-183.

GHS Hazard and Precautionary Statements

Hazard Statements: H331-H302-H312-H315-H319-H335-H227

Toxic if inhaled. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P210-P261-P280-P305+P351+P338-P304+P340-P311-P362-P301+P312-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2930.90
TSCA
Yes

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