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545410-47-7 - 2',5'-Bis(trifluoromethyl)acetophenone, 97% - H26659 - Alfa Aesar

H26659 2',5'-Bis(trifluoromethyl)acetophenone, 97%

CAS Number
545410-47-7
Synonyms

Size Price ($) Quantity Availability
1g 60.70
10g 336.00
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2',5'-Bis(trifluoromethyl)acetophenone, 97%

MDL
MFCD04116044

Chemical Properties

Formula
C10H6F6O
Formula Weight
256.15
Refractive Index
1.4200
Solubility
Sparingly soluble in water.

Applications

Bis(trifluoromethyl)acetophenone is used in the synthesis of the monoamine oxidase-B inhibitors. It is also used to isolate novel bacterial strain from soil samples.

Notes

Incompatible with strong oxidizing agents and strong bases.

Literature References

Kitamura, T.; Muta, K.; Muta, K. Hypervalent Iodine-Promoted α-Fluorination of Acetophenone Derivatives with a Triethylamine·HF Complex. J. Org. Chem. 2014, 79 (12), 5842-5846.

Xiao, H.; Chai, Z.; Yao, R-S.; Zhao, G. Phosphine Catalyst-Controlled Cycloaddition or Dienylation Reactions of Trifluoromethyl Aryl Ketones with Bis-Substituted Allenoates. J. Org. Chem. 2013, 78 (19), 9781-9790.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2914.70
TSCA
No

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