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1122-72-1 - 6-Methylpyridine-2-carboxaldehyde, 98% - 2-Picoline-6-carboxaldehyde - H26841 - Alfa Aesar

H26841 6-Methylpyridine-2-carboxaldehyde, 98%

CAS Number
1122-72-1
Synonyms
2-Picoline-6-carboxaldehyde

Size Price ($) Quantity Availability
5g 126.69
25g 367.20
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6-Methylpyridine-2-carboxaldehyde, 98%

MDL
MFCD00006291
EINECS
214-359-8

Chemical Properties

Formula
C7H7NO
Formula Weight
121.14
Melting point
29-33°
Boiling Point
105-108°/12mm
Flash Point
68°(155°F)
Refractive Index
1.527
Solubility
Soluble in water (750 g/L).

Applications

6-Methyl-2-pyridinecarboxaldehyde was used in the synthesis of 1-(10-cyano- and -10-bromo-5H-dibenzo[a,d]cyclohepten-5-yl)-4-[(arylmethylene)amino]piperazines which are compounds that exhibits anticon vulsant properties. 6-Methylpyridine-2-carboxaldehyde is used to produce 1-(6-methyl-pyridin-2-yl)-hexan-1-one with pent-1-ene at temperature of 100°C. This reaction will need reagent 2-amino-3-picoline and catalysts (Ph3P)3RhCl, Cp2ZrCl2.

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

P. J. Palmer.; R. B. Trigg.; J. V. Warrington. Benzothiazolines as antituberculous agents. J. Med. Chem. 1971, 14, (3), 248-251.

William S. Chilton.; Alice K. Butler. Preparation of aldehyde derivatives from picoline, N-oxides. J. Org. Chem. 1967, 32, (4), 1270-1272.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
107476
Harmonized Tariff Code
2933.39
TSCA
Yes

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