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12289-94-0 - Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) - (1,5-Cyclooctadiene)bis(2-methylallyl)ruthenium(II) - Ruthenium(II) bis(2-methylallyl) 1,5-cyclooctadiene complex - H26891 - Alfa Aesar

H26891 Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)

CAS Number
12289-94-0
Synonyms
(1,5-Cyclooctadiene)bis(2-methylallyl)ruthenium(II)
Ruthenium(II) bis(2-methylallyl) 1,5-cyclooctadiene complex

Size Price ($) Quantity Availability
1g 126.00
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Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)

MDL
MFCD00216965

Chemical Properties

Formula
C16H26Ru
Formula Weight
319.45
Melting point
83-86°
Sensitivity
Air & Moisture Sensitive
Solubility
It is soluble in water.

Applications

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) is used as a catalyst and pharmaceutical intermediate. It is also used as a precatalysts for asymmetric and Cross-Coupling Catalysis reactions, and in organic chemical synthesis.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away strong oxidizing agents.

Literature References

A Fürstner.; OR Thiel.; L Ackermann. Ruthenium carbene complexes with N, N'-bis (mesityl) imidazol-2-ylidene ligands: RCM catalysts of extended scope. J. Org. Chem. 200065 (7), 2204-2207.

LJ Goossen.; M Arndt.; M Blanchot. A Practical and Effective Ruthenium Trichloride-Based Protocol for the Regio-and Stereoselective Catalytic Hydroamidation of Terminal Alkynes. J. Org. Chem. 2008350 (17), 2701-2707.

GHS Hazard and Precautionary Statements

Hazard Statements: H261

In contact with water releases flammable gas.

Precautionary Statements: P231+P232-P280a-P370+P378c-P402+P404-P501a

Handle under inert gas. Protect from moisture. Wear protective gloves and eye/face protection. In case of fire: Use for extinction: CO2, sand, extinguishing powder. Store in a dry place. Store in a closed container. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
III
Harmonized Tariff Code
2843.90
TSCA
No

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