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H26891 Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)

CAS Number
12289-94-0
Synonyms
(1,5-Cyclooctadiene)bis(2-methylallyl)ruthenium(II)
Ruthenium(II) bis(2-methylallyl) 1,5-cyclooctadiene complex

Stock No. Size Price ($) Quantity Availability
H26891-03 1g 129.00
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Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)

MDL
MFCD00216965

Chemical Properties

Formula
C16H26Ru
Formula Weight
319.45
Melting point
83-86°
Storage & Sensitivity
Store at -20°C. Moisture Sensitive. Air Sensitive. Store under Nitrogen.
Solubility
It is soluble in water.

Applications

Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) is used as a catalyst and pharmaceutical intermediate. It is also used as a precatalysts for asymmetric and Cross-Coupling Catalysis reactions, and in organic chemical synthesis.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away strong oxidizing agents.

Literature References

A Fürstner.; OR Thiel.; L Ackermann. Ruthenium carbene complexes with N, N'-bis (mesityl) imidazol-2-ylidene ligands: RCM catalysts of extended scope. J. Org. Chem. 200065 (7), 2204-2207.

LJ Goossen.; M Arndt.; M Blanchot. A Practical and Effective Ruthenium Trichloride-Based Protocol for the Regio-and Stereoselective Catalytic Hydroamidation of Terminal Alkynes. J. Org. Chem. 2008350 (17), 2701-2707.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H332

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P312-P330-P363-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Rinse mouth. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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