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59831-02-6 - Dichloro[bis(1,3-diphenylphosphino)propane]palladium(II) - [1,3-Bis(diphenylphosphino)propane]dichloropalladium(II) - H26897 - Alfa Aesar

H26897 Dichloro[bis(1,3-diphenylphosphino)propane]palladium(II)

CAS Number
59831-02-6
Synonyms
[1,3-Bis(diphenylphosphino)propane]dichloropalladium(II)

Size Price ($) Quantity Availability
250mg 90.00
1g 225.00
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Dichloro[bis(1,3-diphenylphosphino)propane]palladium(II)

MDL
MFCD03844773

Chemical Properties

Formula
C27H26Cl2P2Pd
Formula Weight
589.77
Sensitivity
Air Sensitive
Solubility
Soluble in dichloromethane.

Applications

(1,3-Bis(diphenylphosphino)propane)palladium(II) chloride, used ubiquitously as a employed preparation of palladium for cross-coupling protocols in organic synthesis. It is also a useful organo-metallic chemical catalyst. It is also used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. It is also used in coupling reactions.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away strong oxidizing agents. Air Sensitive.

Literature References

CS Shultz.; J Ledford.; JM DeSimone. Kinetic Studies of Migratory Insertion Reactions at the (1,3-Bis(diphenylphosphino)propane)Pd(II) Center and Their Relationship to the Alternating Copolymerization of Ethylene and Carbon Monoxide. J. Am. Chem. Soc. 2000122 (27), 6351-6356.

M Sundermeier.; A Zapf.; M Beller.; J Sans. A new palladium catalyst system for the cyanation of aryl chlorides. Tetrahedron Letters. 200142 (38), 6707-6710.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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