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4-Bromo-o-phenylenediamine, is used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff.
MA Phillips. The methylation of benziminazoles. Journal of the Chemical Society. 193111 (1), 1143-1153.
EL Samuel. Nitration and bromination products of 2-trifluoromethylbenzimidazoles and their NMR shift assignments. Australian Journal of Chemistry.197225 (12), 2725 - 2729 .
Hazard Statements: H301-H315-H317-H319
Toxic if swallowed. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.
Precautionary Statements: P261-P264b-P270-P272-P280-P301+P310-P302+P352-P305+P351+P338-P330-P333+P313-P337+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant