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97239-80-0 - 1,1'-Bis(diisopropylphosphino)ferrocene, 98% - H27057 - Alfa Aesar

H27057 1,1'-Bis(diisopropylphosphino)ferrocene, 98%

CAS Number
97239-80-0
Synonyms

Size Price ($) Quantity Availability
1g 131.00
5g 479.00
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1,1'-Bis(diisopropylphosphino)ferrocene, 98%

MDL
MFCD02684559

Chemical Properties

Formula
C22H36FeP2
Formula Weight
418.34
Melting point
50-52°
Flash Point
>110°(230°F)
Solubility
Insoluble in water.

Applications

The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1?-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Snegur,; L.V.; Simenel,; A. A.; Rodionov,; A. N.; Boev, V. I. Ferrocene modification of organic compounds for medicinal applications. Russ. Chem. Bull. 2014 , 63 26-36.

Joyce H. L. Ong,; Chip Nataro,; James A. Golen,; Arnold L. Rheingold. Electrochemistry of Late Transition Metal Complexes Containing the Ligand 1,1‘-Bis(diisopropylphosphino)ferrocene (dippf) . Organometallics. 2003, 22(24), 5027-5032.

Other References

Harmonized Tariff Code
2931.90
TSCA
No

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