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H27106 (-)-Bis[(S)-1-phenylethyl]amine, ChiPros®, 99%, ee 98+%

CAS Number
56210-72-1
Synonyms
(-)-Bis[(S)-alpha-methylbenzyl]amine

Stock No. Size Price ($) Quantity Availability
H27106-03 1g 40.30
H27106-06 5g 122.00
H27106-14 25g 443.00
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(-)-Bis[(S)-1-phenylethyl]amine, ChiPros®, 99%, ee 98+%

MDL
MFCD00243087

Chemical Properties

Formula
C16H19N
Formula Weight
225.34
Boiling Point
98°/0.3mm
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
Solubility
Immiscible with water.

Applications

(-)-Bis[(S)-1-phenylethyl]amine is used as a chiral resolution reagent in organic synthesis.

Notes

Incompatible with strong oxidizing agents.

Literature References

Zhuang, Y.; He, Y.; Zhou, Z.; Xia, W.; Cheng, C.; Wang, M.; Chen, B.; Zhou, Z.; Pang, J.; Qiu, L. Synthesis of a Class of Chiral-Bridged Phosphoramidite Ligands and Their Applications in the First Iridium-Catalyzed Asymmetric Addition of Arylboronic Acids to Isatins. J. Org. Chem. 2015, 80 (14), 6968-6975.

Dayaker, G.; Tilly, D.; Chevallier, F.; Hilmersson, G.; Gros, P. C.; Mongin, F. Enantioselective Metalation of N,N-Diisopropylferrocenecarboxamide and Methyl Ferrocenecarboxylate Using Lithium-Metal Chiral Bases. Eur. J. Org. Chem. 2012, 2012 (30), 6051-6057.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2921.49
TSCA
No

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