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56210-72-1 - (-)-Bis[(S)-1-phenylethyl]amine, ChiPros®, 99%, ee 98+% - (-)-Bis[(S)-alpha-methylbenzyl]amine - H27106 - Alfa Aesar

H27106 (-)-Bis[(S)-1-phenylethyl]amine, ChiPros®, 99%, ee 98+%

CAS Number
56210-72-1
Synonyms
(-)-Bis[(S)-alpha-methylbenzyl]amine

Size Price ($) Quantity Availability
1g 38.42
5g 116.39
25g 434.66
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(-)-Bis[(S)-1-phenylethyl]amine, ChiPros®, 99%, ee 98+%

MDL
MFCD00243087

Chemical Properties

Formula
C16H19N
Formula Weight
225.34
Boiling Point
98°/0.3mm
Solubility
Immiscible with water.

Applications

(-)-Bis[(S)-1-phenylethyl]amine is used as a chiral resolution reagent in organic synthesis.

Notes

Incompatible with strong oxidizing agents.

Literature References

Zhuang, Y.; He, Y.; Zhou, Z.; Xia, W.; Cheng, C.; Wang, M.; Chen, B.; Zhou, Z.; Pang, J.; Qiu, L. Synthesis of a Class of Chiral-Bridged Phosphoramidite Ligands and Their Applications in the First Iridium-Catalyzed Asymmetric Addition of Arylboronic Acids to Isatins. J. Org. Chem. 2015, 80 (14), 6968-6975.

Dayaker, G.; Tilly, D.; Chevallier, F.; Hilmersson, G.; Gros, P. C.; Mongin, F. Enantioselective Metalation of N,N-Diisopropylferrocenecarboxamide and Methyl Ferrocenecarboxylate Using Lithium-Metal Chiral Bases. Eur. J. Org. Chem. 2012, 2012 (30), 6051-6057.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2921.49
TSCA
No

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