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343338-28-3 - (S)-(-)-2-Methyl-2-propanesulfinamide, 97% - (S)-(-)-tert-Butyl sulfinamide - H27115 - Alfa Aesar

H27115 (S)-(-)-2-Methyl-2-propanesulfinamide, 97%

CAS Number
343338-28-3
Synonyms
(S)-(-)-tert-Butyl sulfinamide

Size Price ($) Quantity Availability
1g 61.86
5g 206.86
25g 803.40
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(S)-(-)-2-Methyl-2-propanesulfinamide, 97%

MDL
MFCD05861480

Chemical Properties

Formula
C4H11NOS
Formula Weight
121.20
Melting point
97-101°

Applications

(S)-(-)-2-Methyl-2-propanesulfinamide is used in Suzuki reaction. It is also employed as a reagent for synthesizing chiral amines. It acts as a chiral auxiliary used in an asymmetric synthesis of trifluoroethylamines by conversion of trifluoroacetaldehyde to a chiral imine. It is also involved in the transformation of P,N-sulfinyl imine ligands through condensation with aldehydes and ketones, which can undergo iridium-catalyzed asymmetric hydrogenation of olefins. Further, it serves as a reagent for the preparation of chemicals and pharmaceutical intermediates.

Notes

Incompatible with strong oxidizing agents. Store in a cool place.

Literature References

Liu, Z.; Liu, F.; Aldrich, C. C. Stereocontrolled Synthesis of a Potential Transition-State Inhibitor of the Salicylate Synthase MbtI from Mycobacterium tuberculosis. J. Org. Chem. 2015, 80 (13), 6545-6552.

Sanchez-Rosello, M.; Delgado, O.; Mateu, N.; Trabanco, A. A.; Van Gool, M.; Fustero, S. Diastereoselective Synthesis of 2-Phenyl-3-(trifluoromethyl)piperazines as Building Blocks for Drug Discovery. J. Org. Chem. 2014, 79 (12), 5887-5894.

Other References

Harmonized Tariff Code
2930.90
TSCA
No

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