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30282-14-5 - 2-Hydroxycyclohexanone dimer, 90+% - Adipoin - H27199 - Alfa Aesar

H27199 2-Hydroxycyclohexanone dimer, 90+%

CAS Number
30282-14-5
Synonyms
Adipoin

Size Price ($) Quantity Availability
1g 21.22
5g 51.91
25g 118.80
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2-Hydroxycyclohexanone dimer, 90+%

MDL
MFCD00151157

Chemical Properties

Formula
C12H20O4
Formula Weight
228.28
Melting point
100-107°
Boiling Point
83-86°/13mm
Flash Point
79°(174°F)
Solubility
Partly miscible in water.

Applications

It is a reactant involved in the synthesis of substrates for tin tetrachloride mediated fragmentation to produce ynones and ynoates, tandem oxidation coupling reactions with diamines, asymmetric allylic alkylation of enolates and formate reduction of allylic carbonates for polypropionate systems.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Keep away from ignition sources. Protect from electrostatic charges. Ensure adequate ventilation.

Literature References

Barry M Trost, et al. Enantioselective synthesis of alpha-tertiary hydroxyaldehydes by palladium-catalyzed asymmetric allylic alkylation of enolates.J Am Chem Soc.,2009,129(2), 282-3.

Ali Bayir, et al. Preparation of tethered aldehyde ynoates and ynones by ring fragmentation of cyclic gamma-oxy-beta-hydroxy-alpha-diazo carbonyls.J Org Chem.,2010,75(2), 296-302.

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H315-H319-H335

Flammable solid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P280g-P305+P351+P338

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Hazard Class
4.1
Packing Group
III
Harmonized Tariff Code
2932.99
TSCA
No

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