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85100-77-2 - 1-n-Butyl-3-methylimidazolium bromide, 99% - BMIMBr - H27201 - Alfa Aesar

H27201 1-n-Butyl-3-methylimidazolium bromide, 99%

CAS Number
85100-77-2
Synonyms
BMIMBr

Size Price ($) Quantity Availability
5g 36.67
50g 102.69
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1-n-Butyl-3-methylimidazolium bromide, 99%

MDL
MFCD03427611

Chemical Properties

Formula
C8H15BrN2
Formula Weight
219.12
Melting point
65-75°
Sensitivity
Hygroscopic
Solubility
Miscible in water, methanol and dichloromethane. Immiscible in acetone, toluene, ethyl acetate and diethyl ether.

Applications

It is an ionic liquid used in a Heck reaction. It is also used in assessing the factors responsible for ionic liquid toxicity to aquatic organisms via quantitative structure-property relationship modeling

Notes

Hygroscopic. Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

M. Teresa Garcia, et al. Biodegradable ionic liquids Part II. Effect of the anion and toxicology.Green Chem.,2005,7(1), 9-14.

Miriam Kohagen, et al. How Hydrogen Bonds Influence the Mobility of Imidazolium-Based Ionic Liquids. A Combined Theoretical and Experimental Study of 1-n-Butyl-3-methylimidazolium Bromide.J. Phys. Chem. B.,2011,115(51), 15280-15288.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319

Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P280-P264-P305+P351+P338-P362-P321-P332+P313-P337+P313-P302+P352

Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: IF ON SKIN: Wash with plenty of soap and water.

Other References

Harmonized Tariff Code
2933.29
TSCA
No

Recommended

  • H27651

    1-Ethyl-3-methylimidazolium chloride, 98+%
  • L19086

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  • L19749

    1-n-Butyl-3-methylimidazolium chloride, 96%
  • L19761

    1-Ethyl-3-methylimidazolium bromide, 98+%
  • L19763

    1-Ethyl-3-methylimidazolium tetrafluoroborate, 98+% (dry wt.), may cont. up to 3% water

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