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It is applied as a reactant for synthesis of ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation, metallocene-bridged bisphosphaalkene and as a catalyst for synthesis of oligonuclear heterometallic complexes.
Carmen Moser, et. al. The homologous series of 1,1'-ferrocenylenebisdihalophosphanes (C5H4PX2)2Fe (X = F, Cl, Br, I): precursors for the first metallocene bridged bisphosphaalkene.Dalton Trans.,2006,732(7), 3879-3885.
Xingao Peng, et al. Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation.Tetrahedron Lett.,2008,49(33), 4862-4864.
Hazard Statements: H314-H318
Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.