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142691-70-1 - 1,1'-Bis(dichlorophosphino)ferrocene, 98% - H27293 - Alfa Aesar

H27293 1,1'-Bis(dichlorophosphino)ferrocene, 98%

CAS Number
142691-70-1
Synonyms

Size Price ($) Quantity Availability
250mg 59.10
1g 146.00
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1,1'-Bis(dichlorophosphino)ferrocene, 98%

MDL
MFCD01630854

Chemical Properties

Formula
C10H8Cl4FeP2
Formula Weight
387.78
Sensitivity
Moisture Sensitive
Solubility
Reacts with water.

Applications

It is applied as a reactant for synthesis of ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation, metallocene-bridged bisphosphaalkene and as a catalyst for synthesis of oligonuclear heterometallic complexes.

Notes

Moisture sensitive. Store away from water/moisture, strong bases and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

Literature References

Carmen Moser, et. al. The homologous series of 1,1'-ferrocenylenebisdihalophosphanes (C5H4PX2)2Fe (X = F, Cl, Br, I): precursors for the first metallocene bridged bisphosphaalkene.Dalton Trans.,2006,732(7), 3879-3885.

Xingao Peng, et al. Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation.Tetrahedron Lett.,2008,49(33), 4862-4864.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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