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90076-65-6 - Lithium bis(trifluoromethylsulfonyl)imide, 98+% - Bis(trifluoromethane)sulfonimide lithium salt - Lithium bis(trifluoromethanesulfonyl)imide - H27307 - Alfa Aesar

H27307 Lithium bis(trifluoromethylsulfonyl)imide, 98+%

CAS Number
90076-65-6
Synonyms
Bis(trifluoromethane)sulfonimide lithium salt
Lithium bis(trifluoromethanesulfonyl)imide

Size Price ($) Quantity Availability
10g 59.84
50g 183.34
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Lithium bis(trifluoromethylsulfonyl)imide, 98+%

MDL
MFCD00210017
EINECS
415-300-0

Chemical Properties

Formula
C2F6LiNO4S2
Formula Weight
287.08
Melting point
234-238°
Sensitivity
Moisture Sensitive
Solubility
Soluble in water.

Applications

Lithium bis(trifluoromethylsulfonyl)imide is used in the preparation of chiral imidazolium salt through an anion metathesis of the corresponding triflate organic electrolyte-based lithium batteries. It finds application in the preparation of rare-earth Lewis acid catalysts. It is also useful in primary and secondary lithium cells using organic liquid electrolytes and polymer batteries.

Notes

Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Literature References

Motomatsu, J.; Kodama, H.; Furukawa, T.; Tominaga, Y. Dielectric Relaxation Behavior of a Poly (ethylene carbonate)-Lithium Bis-(trifluoromethanesulfonyl) Imide Electrolyte. Macromol. Chem. Phys. 2015, 216, (15), 1660-1665.

Pehlivan, I. B.; Granqvist, C. G.; Niklasson, G. A. Ion conduction mechanism of nanocomposite polymer electrolytes comprised of polyethyleneimine-lithium bis (trifluoromethylsulfonyl) imide and silica. Electrochim. Acta 2014, 119, 164-168.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H314-H373-H412

Toxic if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. May cause damage to organs through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects.

Precautionary Statements: P260-P273-P280-P301+P310-P303+P361+P353-P305+P351+P338-P361-P301+P330+P331-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2935.00
TSCA
Yes

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