Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

2526-64-9 - Triphenylphosphine dichloride, 96% - Dichlorotriphenylphosphorane - H27436 - Alfa Aesar

H27436 Triphenylphosphine dichloride, 96%

CAS Number
2526-64-9
Synonyms
Dichlorotriphenylphosphorane

Size Price ($) Quantity Availability
25g 43.10
100g 144.00
Add to Cart Add to Quote Request View Item

Triphenylphosphine dichloride, 96%

MDL
MFCD00010359

Chemical Properties

Formula
(C6H5)3PCl2
Formula Weight
333.19
Melting point
84-86°
Sensitivity
Moisture Sensitive
Solubility
Reacts with water.

Applications

As a precursor to fire-retardant materials. Mainly used as a chlorinating agent widely used in organic chemistry. Applications include the conversion of alcohols and ethers to alkyl chlorides, the cleavage of epoxides to vicinal dichlorides and the chlorination of carboxylic acids to acyl chlorides.

Notes

Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, bases, air, moisture.

Literature References

Shinichiro Kitayama,; Kohei Sanui,; Naoya Ogata. Synthesis of aromatic polyesters by direct polycondensation with triphenylphosphine dichloride. Journal of Polymer Science. 1984, 22 (10), 2705-2712.

Tomotake Yano,; Manabu Kuroboshi,; Hideo Tanaka. Electroreduction of triphenylphosphine dichloride and the efficient one-pot reductive conversion of phosphine oxide to triphenylphosphine. Tetrahedron Letters. 2010 , 51(4),698-701.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware