Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

50816-19-8 - 8-Bromo-1-octanol, 95% - Octamethylene bromohydrin - H27628 - Alfa Aesar

H27628 8-Bromo-1-octanol, 95%

CAS Number
50816-19-8
Synonyms
Octamethylene bromohydrin

Size Price ($) Quantity Availability
1g 46.80
5g 148.00
25g 460.00
Add to Cart Add to Quote Request View Item

8-Bromo-1-octanol, 95%

MDL
MFCD00010388
EINECS
256-785-7

Chemical Properties

Formula
C8H17BrO
Formula Weight
209.13
Boiling Point
79-80°/0.07mm
Flash Point
>110°(230°F)
Density
1.220
Refractive Index
1.4810

Applications

It is used to produce 8-phenylselanyl-octan-1-ol by reaction with diphenyl-diselane. The reaction occurs with reagent sodium borohydride and solvent ethanol at ambient temperature. The yield is about 96%. 8-Bromo-1-octanol was used in the synthesis of (E)-10-hydroxy-2-decenoic acid (royal jelly acid)1. It was also used in the synthesis of (Z)-14-methyl-9-pentadecenoic acid.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents. Refrigerated (4°C).

Literature References

R Chiron. New synthesis of royal jelly acid.. Journal of Chemical Ecology. 1982, 8 (4), 709-713

Carballeira NM,; Sanabria D,;Oyola D. An improved synthesis for the (Z)-14-methyl-9-pentadecenoic acid and its topoisomerase I inhibitory activity. ARKIVOC. 2007, 8 (49-57).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319

Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P280a-P264-P305+P351+P338-P321-P332+P313-P337+P313

Wear protective gloves and eye/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists:

Other References

Beilstein
1900837
Harmonized Tariff Code
2905.59
TSCA
Yes

Recommended

  • A11806

    Nitromethane, 98+%
  • A18395

    Sodium hydroxide, flake, 98%
  • A18613

    2-Chlorocyclohexanone, 97%, stab. with calcium carbonate/magnesium oxide
  • A18862

    2-Dodecanone, 95%
  • B25165

    Trimethylenebis(triphenylphosphonium bromide), 98+%

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware