Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

H27772 Methyl hydrogen malonate, 96%

CAS Number
16695-14-0
Synonyms
Malonic acid monomethyl ester
Monomethyl malonate

Stock No. Size Price ($) Quantity Availability
H27772-06 5g 48.70
H27772-14 25g 136.00
H27772-22 100g 410.00
Add to Cart Bulk/Specialty Print Quote View Item

Methyl hydrogen malonate, 96%

MDL
MFCD00667796

Chemical Properties

Formula
HO2CCH2CO2CH3
Formula Weight
118.09
Density
1.128
Refractive Index
1.4295
Storage & Sensitivity
Keep Cold.

Applications

Lactonization of olefins with monomethyl ester of malonic acid and ceric ammonium nitrate was carried out in acetic acid and in acetonitrile under simple mechanical stirring or ultrasound irradiation. Lactonization of olefins with CAN and monomethyl ester of malonic acid under ultrasound irradiation shows an acceleration with respect to the analogous mechanically stirred reaction.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Andrea D'Annibale,; Corrado Trogolo. Sonochemical lactonization of olefins with ceric ammonium nitrate and monomethyl ester of malonic acid. Tetrahedron Letters. 1994, 35(13), 2083-2086.

Zoltan. Noszticzius,; William D. McCormick,; Harry L. Swinney. Effect of trace impurities on a bifurcation structure in the Belousov-Zhabotinskii reaction: preparation of high-purity malonic acid. J. Phys. Chem. 1987, 91 (19), 5129-5134.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2917.19
TSCA
No

Recommended

  • A10342

    3-(2-Thienyl)acrylic acid, predominantly trans, 98+%
  • A11032

    Chloroiodomethane, 98%, stab. with copper
  • A13933

    Bromoacetonitrile, 96%
  • A14215

    Cyclopropanecarboxylic acid, 98%
  • A14747

    trans-3-(3-Pyridyl)acrylic acid, 99%

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware