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In the resolution system of (RS)-1-cyclohexylethylamine (CHEA) with (S)-mandelic acid (MA), the DCR (dielectrically controlled resolution) phenomenon was clearly observed.
Bingzhi Shi,; Tanjore K Narayanan,; Zhi-Ying Yang,; Bradley T Christian,; Jogeshwar Mukherjee. Radiosynthesis and in vitro evaluation of 2-(N-alkyl-N-1?-11C-propyl)amino-5-hydroxytetralin analogs as high affinity agonists for dopamine D-2 receptors. Nuclear Medicine and Biology. 1999, 26 (7),725-735.
Beverly A Clement,; Christina M Goff,; T.David A Forbes. Toxic amines and alkaloids from acacia rigidula Phytochemistry. 1998, 49 (5),1377-1380.
Kenichi Sakaia,; Rumiko Sakuraia,; Noriaki Hirayama. Molecular mechanism of DCR phenomenon observed in (RS)-1-cyclohexylethylamine-mandelic acid resolution system. Tetrahedron: Asymmetry. 2006, 17 (12),1812-1816.
Hazard Statements: H314-H318
Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.