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Dimethylphenylsilane was catalytically dehydrogenated and condensed in the presence of platinum complexes to give 1,1,2,2-tetramethyl-1,2-diphenyl-disilane.
Masato Tanaks,; Toshi-Aki Kobayashi,; Teruyuki Hayashi,;Toshiyasu Sakakura. Dehydrogenative condensation of monohydrosilanes yielding disilanes in the presence of platinum complex catalysts. Applied Organometallic Chemistry. 1988, 2(1), 91-92.
Hajime Ito,; Tomoko Ishizuka,; Jun-ichi Tateiwa,; Motohiro Sonoda,; Akira Hosomi,;. New Method for Introduction of a Silyl Group into α,β-Enones Using a Disilane Catalyzed by a Copper(I) Salt1 . J. Am. Chem. Soc. 1998, 120 (43),11196-11197.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant