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H28782 5-(Trifluoromethyl)indole, 98%

CAS Number
100846-24-0
Synonyms

Stock No. Size Price ($) Quantity Availability
H28782-MC 100mg 85.60
H28782-ME 500mg 261.00
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5-(Trifluoromethyl)indole, 98%

MDL
MFCD03095341

Chemical Properties

Formula
C9H6F3N
Formula Weight
185.15
Melting point
68-71°
Storage & Sensitivity
Ambient temperatures.

Applications

In 3-Naphthylindole construction by rhodium (II)-catalyzed regioselective direct arylation of indoles with 1-diazonaphthalen-2-(1H)-ones treatment of 5-(trifluoromethyl)indole(1k) or 6-(trifluoromethyl)indole (1l) with 2a afforded the desired products 3k (86%)and 3l (86%).

Notes

Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, light.

Literature References

Ek Raj Baral,; Yong Rok Lee1,; Sung Hong Kim2. 3-Naphthylindole Construction by Rhodium(II)-Catalyzed Regioselective Direct Arylation of Indoles with 1-Diazonaphthalen-2-(1H)-ones. Advanced Synthesis & Catalysis. 2015, 357 (13),2883-2892.

Larisa V. Politanskaya,; Igor P. Chuikov,; Vitalij D. Shteingarts. Synthesis of indoles with a polyfluorinated benzene ring . Tetrahedron. 2013 , 69 (39),8477-8486.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2933.99
TSCA
No

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