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114360-54-2 - N-Fmoc-D-leucine, 98% - N-(9-Fluorenylmethoxy)carbonyl-D-leucine - Fmoc-D-Leu-OH - H29041 - Alfa Aesar

H29041 N-Fmoc-D-leucine, 98%

CAS Number
114360-54-2
Synonyms
N-(9-Fluorenylmethoxy)carbonyl-D-leucine
Fmoc-D-Leu-OH

Size Price ($) Quantity Availability
1g 22.96
5g 88.68
25g 289.43
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N-Fmoc-D-leucine, 98%

MDL
MFCD00062957

Chemical Properties

Formula
C21H23NO4
Formula Weight
353.42
Melting point
151-154°
Solubility
Insoluble in water.

Applications

A convergent synthesis of the proposed structure of (+)-pestalazine B has been achieved in 4 steps using the N-alkylation of an unprotected tryptophan diketopiperazine with a 3a-bromopyrrolidinoindoline where the condensation between L-tryptophan methyl ester and N-Fmoc-D-leucine in the presence of EDC as coupling agent afforded the corresponding L-Trp-D-Leu dipeptide.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Carlos Pérez-Baladoa,; Ángel R. de Lera. Concise total synthesis and structural revision of (+)-pestalazine B. Org. Biomol. Chem. 2010, 8 5179-5186.

Zhimou Yang et. al. Self-assembly of small molecules affords multifunctional supramolecular hydrogels for topically treating simulated uranium wounds. Chemical Communications. 2005, 35 4414-4416 .

Other References

Harmonized Tariff Code
2924.29
TSCA
No

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