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628-92-2 - Cycloheptene, 96%, stab. with 0.1% BHT - H29062 - Alfa Aesar

H29062 Cycloheptene, 96%, stab. with 0.1% BHT

CAS Number
628-92-2
Synonyms

Size Price ($) Quantity Availability
5g 96.31
25g 254.70
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Cycloheptene, 96%, stab. with 0.1% BHT

MDL
MFCD00004156
EINECS
211-060-4

Chemical Properties

Formula
C7H12
Formula Weight
96.17
Boiling Point
112-115°
Flash Point
-7°(19°F)
Density
0.833
Refractive Index
1.458
Solubility
Insoluble in water.

Applications

Cycloheptene was used in one-pot synthesis of 1,2/3-triols from the allylichydroperoxides catalyzed by zeolite-confined osmium(0) nanoclusters. It is a raw material in organic chemistry and a monomer in polymer synthesis. Copper (1) triflate catalyzes the photodimerization of the simple nonconjugated unstrained olefins, cyclopentene, cyclohexene, and cycloheptene, but not cyclooctene or acyclic olefins.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, acids. May react exothermically with reducing agents to release hydrogen gas.

Literature References

Göksu H, et al. J. . One-pot synthesis of 1, 2/3-triols from the allylic hydroperoxides catalyzed by zeolite-confined osmium (0) nanoclusters. Mol. Catal. A: Chem.. 2013, 378 142-147.

Robert G. Salomon,; Kirsten Folting,; William E. Streib,; Jay K. Kochi. Copper(I) catalysis in photocycloadditions. II. Cyclopentene, cyclohexene, and cycloheptene. J. Am. Chem. Soc. 1974, 96(4),1145-1152.

GHS Hazard and Precautionary Statements

Hazard Statements: H225

Highly flammable liquid and vapour.

Precautionary Statements: P210-P280-P240-P241-P233-P242-P243-P303+P361+P353-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Keep container tightly closed. Use only non-sparking tools. Take precautionary measures against static discharge. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2902.19
TSCA
No

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