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H nmr spectral parameters are reported for salicylaldehyde and 15 of its derivatives in dilute CCl4 solutions, a positive spin-spin coupling is observed between the two sidechain protons.
Ted Schaefer,; Rudy Sebastian,; Reino Laatikainen,; Salman R. Salman. Spin-spin coupling between hydroxyl and aldehydic protons in some salicylaldehyde derivatives. Correlation with the hydroxyl proton chemical shift. Canadian Journal of Chemistry,. 1984 , 62(2),326-331.
Verónica Ferraresi-Curotto et. al. Structural, spectroscopic and DFT study of 4-methoxybenzohydrazide Schiff bases. A new series of polyfunctional ligands. pectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2015, 137 692-700
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.