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H30110 Benzophenone imine, 95%

CAS Number
1013-88-3
Synonyms

Stock No. Size Price ($) Quantity Availability
H30110-06 5g 53.40
H30110-14 25g 140.00
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Benzophenone imine, 95%

MDL
MFCD00001760

Chemical Properties

Formula
C13H11N
Formula Weight
181.23
Boiling Point
151-153°/10mm
Density
1.08
Refractive Index
1.6180
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

Useful in the preparation of nitrile ylide dimers.Benzophenone imine as ammonia surrogate. As intermediate material for synthesis of organic chemicals. Catalytic enantioselective alkylation of the benzophenone imine of glycine t-butyl ester using phosphazene (Schwesinger) bases and chiral quaternary ammonium salts yields either enantiomer of amino acid derivatives in excellent yield.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Suzanne Fergus et. al. Nitrile ylide dimerization: investigation of the carbene reactivity of nitrile ylides.. Journal of Organic Chemistry. 2004, 69 (14),4663-4669.

C. R. Noller. Diphenylmethane inime hydrochloride. Org. Synth. 10 (28).

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
9
Packing Group
III
Harmonized Tariff Code
2925.29
TSCA
No

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