Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

1013-88-3 - Benzophenone imine, 95% - H30110 - Alfa Aesar

H30110 Benzophenone imine, 95%

CAS Number
1013-88-3
Synonyms

Size Price ($) Quantity Availability
5g 47.16
25g 136.99
Add to Cart Add to Quote Request View Item

Benzophenone imine, 95%

MDL
MFCD00001760

Chemical Properties

Formula
C13H11N
Formula Weight
181.23
Boiling Point
151-153°/10mm
Density
1.08
Refractive Index
1.6180
Solubility
Insoluble in water.

Applications

Useful in the preparation of nitrile ylide dimers.Benzophenone imine as ammonia surrogate. As intermediate material for synthesis of organic chemicals. Catalytic enantioselective alkylation of the benzophenone imine of glycine t-butyl ester using phosphazene (Schwesinger) bases and chiral quaternary ammonium salts yields either enantiomer of amino acid derivatives in excellent yield.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Suzanne Fergus et. al. Nitrile ylide dimerization: investigation of the carbene reactivity of nitrile ylides.. Journal of Organic Chemistry. 2004, 69 (14),4663-4669.

C. R. Noller. Diphenylmethane inime hydrochloride. Org. Synth. 10 (28).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2925.29
TSCA
No

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware