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H30222 Methyl 3-bromo-4-hydroxybenzoate, 98%

CAS Number
3-Bromo-4-hydroxybenzoic acid methyl ester

Stock No. Size Price ($) Quantity Availability
H30222-09 10g 45.60
H30222-18 50g 180.00
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Methyl 3-bromo-4-hydroxybenzoate, 98%


Chemical Properties

Formula Weight
Melting point
Storage & Sensitivity
Ambient temperatures.


A reactant used in the preparation of selective inhibitors. In unsymmetrical Ullman reaction between methyl 5bromovanillate (II) and methyl 3-bromo-4-hydroxybenzoate (III) yielded all the three possible dicarbomethoxy-dibenzo-pdioxms which were separated by repeated chromatography over silica gel. A phosphorus- and bromine-containing bifunctional monomer has been prepared from bis(chloromethyl)methylphosphine oxide and the sodium salt of methyl 3-bromo-4-hydroxybenzoate.


Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

H. Sivriev ,; G. Borissov ,; T.E. Kron,; E.N. Tsvetkov,; M.I. Kabachnik. Polyesters based on bromine-containing bis(p-methoxycarbonylphenoxymethyl)-methylphosphine oxide. European Polymer Journal. 15 (8),771-774.

B. Anjaneyulu,; T.R. Govindachari,; N. Viswanathan.Total synthesis of dl-O-methyltiliacorine . Tetrahedron. 1971, 27 (2) , 439-443.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code


  • A13128

    Methyl acrylate, 99%, stab. with ca 15ppm 4-methoxyphenol
  • A19638

    1-Tetradecanol, 97+%
  • B22710

    3-(Ethylthio)propanol, 97%
  • H61219

    Methyl 3-fluoro-4-hydroxybenzoate, 98%
  • H63286

    2-Bromobenzothiazole, 99%

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