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29415-97-2 - Methyl 3-bromo-4-hydroxybenzoate, 98% - 3-Bromo-4-hydroxybenzoic acid methyl ester - H30222 - Alfa Aesar

H30222 Methyl 3-bromo-4-hydroxybenzoate, 98%

CAS Number
3-Bromo-4-hydroxybenzoic acid methyl ester

Size Price ($) Quantity Availability
10g 44.60
50g 178.19
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Methyl 3-bromo-4-hydroxybenzoate, 98%


Chemical Properties

Formula Weight
Melting point


A reactant used in the preparation of selective inhibitors. In unsymmetrical Ullman reaction between methyl 5bromovanillate (II) and methyl 3-bromo-4-hydroxybenzoate (III) yielded all the three possible dicarbomethoxy-dibenzo-pdioxms which were separated by repeated chromatography over silica gel. A phosphorus- and bromine-containing bifunctional monomer has been prepared from bis(chloromethyl)methylphosphine oxide and the sodium salt of methyl 3-bromo-4-hydroxybenzoate.


Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

H. Sivriev ,; G. Borissov ,; T.E. Kron,; E.N. Tsvetkov,; M.I. Kabachnik. Polyesters based on bromine-containing bis(p-methoxycarbonylphenoxymethyl)-methylphosphine oxide. European Polymer Journal. 15 (8),771-774.

B. Anjaneyulu,; T.R. Govindachari,; N. Viswanathan.Total synthesis of dl-O-methyltiliacorine . Tetrahedron. 1971, 27 (2) , 439-443.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code


  • A13128

    Methyl acrylate, 99%, stab. with ca 15ppm 4-methoxyphenol
  • A19638

    1-Tetradecanol, 97+%
  • B22710

    3-(Ethylthio)propanol, 97%
  • H61219

    Methyl 3-fluoro-4-hydroxybenzoate, 98%
  • H63286

    2-Bromobenzothiazole, 99%

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