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124215-44-7 - 3-Bromopropylboronic acid pinacol ester, 98% - 2-(3-Bromopropyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane - H30646 - Alfa Aesar

H30646 3-Bromopropylboronic acid pinacol ester, 98%

CAS Number
124215-44-7
Synonyms
2-(3-Bromopropyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Size Price ($) Quantity Availability
1g 38.70
5g 148.50
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3-Bromopropylboronic acid pinacol ester, 98%

MDL
MFCD10567053

Chemical Properties

Formula
C9H18BBrO2
Formula Weight
248.96
Boiling Point
61-64°/0.35mm
Density
1.177
Solubility
Not miscible or difficult to mix with water.

Applications

Used as primary and secondary intermediate for pharmaceutical.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

H W Man; W C Hiscox; D S Matteson. A highly enantioselective and diastereoselective synthesis of cyclobutanes via boronic esters. Organic Letters,1999, 1(3), 379-381.

Pavel K. Elkin; Vitalij V. Levin; Alexander D. Dilman; Marina I. Struchkova; Pavel A. Belyakov; Dmitry E. Arkhipov; Alexander A. Korlyukov; Vladimir A. Tartakovsky. Reactions of CF3-substituted boranes with α-diazocarbonyl compounds. Tetrahedron Letters,2011, 52(41), 5259-5263.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319

Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Harmonized Tariff Code
2934.99
TSCA
No

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