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H30770 tert-Butyl vinyl ether, 98%, stab. with ca 0.1% N,N-diethylaniline

CAS Number
926-02-3
Synonyms
2-Methyl-2-vinyloxypropane

Stock No. Size Price ($) Quantity Availability
H30770-06 5g 61.10
H30770-14 25g 188.00
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tert-Butyl vinyl ether, 98%, stab. with ca 0.1% N,N-diethylaniline

MDL
MFCD00048246
EINECS
618-860-6

Chemical Properties

Formula
C6H12O
Formula Weight
100.16
Boiling Point
75-76°
Flash Point
-17°(1°F)
Density
0.762
Refractive Index
1.3990
Storage & Sensitivity
Keep Cold.
Solubility
Miscible with alcohol, carbon disulfide, chloroform and diethyl ether. Slightly miscible with water.

Applications

tert-Butyl vinyl ether is used in the synthesis of 3-tert-Butoxycyclobutanone by reacting with ketene using zinc(II) chloride as a catalyst. It acts as an intermediate for the functional vinyl monomer.

Notes

Incompatible with strong oxidizing agents.

Literature References

Han, D.; Cao, H.; Li, J.; Li, M.; Li, X.; He, M.; Hu, J. Theoretical studies on the mechanisms and rate constants for the hydroxylation of n-butyl, iso-butyl and tert-butyl vinyl ethers in atmosphere. Struct. Chem. 2015, 26 (3), 713-729.

Najera, C.; Sansano, J. M.; Yus, M. 1,3-Dipolar cycloadditions of azomethine imines. Org. Biomol. Chem. 2015, 13 (32), 8596-8636.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H315-H319

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P264b-P280-P303+P361+P353-P305+P351+P338-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2909.19
TSCA
Yes

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