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It is the intermediate of Voglibose/Dapagliflozin. An important D-glucopyranose derivative for glucosylations and other reactions 1,2; Preparation of the α-glucopyranosyl chloride, synthesis of 1-C-α-D-glucopyranose derivatives.
Philip E. Pfeffer; Edward S. Rothman; Gordon G. Moore. Stereochemical control in the acylation of 2,3,4,6-tetra-O-benzyl-D-glucopyranose. A route to 1-O-acyl-.alpha.- and -.beta.-D-glucopyranoses. J. Org. Chem. 1976, 41 (17), 2925-2927.
Pietro Allevi; Pierangela Ciuffreda; Diego Colombo; Diego Monti; Giovanna Speranza and Paolo Manitto. The Wittig-Horner reaction on 2,3,4,6-tetra-O-benzyl-D-mannopyranose and 2,3,4,6-tetra -O-benzyl-D-glucopyranose. J. Chem. Soc., Perkin Trans. 1. 1989, (7), 1281-1283.