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6564-72-3 - 2,3,4,6-Tetra-O-benzyl-alpha-D-glucopyranose, 98% - H31595 - Alfa Aesar

H31595 2,3,4,6-Tetra-O-benzyl-alpha-D-glucopyranose, 98%

CAS Number
6564-72-3
Synonyms

Size Price ($) Quantity Availability
1g 44.91
5g 170.98
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2,3,4,6-Tetra-O-benzyl-alpha-D-glucopyranose, 98%

MDL
MFCD00023849

Chemical Properties

Formula
C34H36O6
Formula Weight
540.65
Melting point
150-151°
Solubility
Soluble in CHCl3. Insoluble in water.

Applications

It is the intermediate of Voglibose/Dapagliflozin. An important D-glucopyranose derivative for glucosylations and other reactions 1,2; Preparation of the α-glucopyranosyl chloride, synthesis of 1-C-α-D-glucopyranose derivatives.

Notes

Store in cool, dry place in a well sealed container. Store away from oxidizing agents.

Literature References

Philip E. Pfeffer; Edward S. Rothman; Gordon G. Moore. Stereochemical control in the acylation of 2,3,4,6-tetra-O-benzyl-D-glucopyranose. A route to 1-O-acyl-.alpha.- and -.beta.-D-glucopyranoses. J. Org. Chem. 1976, 41 (17), 2925-2927.

Pietro Allevi; Pierangela Ciuffreda; Diego Colombo; Diego Monti; Giovanna Speranza and Paolo Manitto. The Wittig-Horner reaction on 2,3,4,6-tetra-O-benzyl-D-mannopyranose and 2,3,4,6-tetra -O-benzyl-D-glucopyranose. J. Chem. Soc., Perkin Trans. 1. 1989, (7), 1281-1283.

Other References

Harmonized Tariff Code
2940.00
TSCA
No

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