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H31830 Titanium(IV) chloride, 1M soln. in dichloromethane

CAS Number
7550-45-0
Synonyms
Titanium tetrachloride
Titanic chloride

Stock No. Size Price ($) Quantity Availability
H31830-AE 100ml 44.20
H31830-AP 500ml 148.00
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Titanium(IV) chloride, 1M soln. in dichloromethane

MDL
MFCD00011267

Chemical Properties

Formula
Cl4Ti
Formula Weight
189.69
Density
1.365
Storage & Sensitivity
Store under Nitrogen. Moisture Sensitive. May form a Precipitate. Ambient temperatures.
Solubility
Reacts with water.

Applications

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines

Notes

Moisture Sensitive. Keep container tightly closed. Store in cool, dry conditions in well sealed containers

Literature References

Min Shi.; Jian-Kang Jiang.; Yan-Shu Feng. Titanium(IV) Chloride and the Amine-Promoted Baylis-Hillman Reaction. Org. Lett. 2000, 16, (2), 2397-2400.

Min Shi.; Yan-Shu Feng. Titanium(IV) Chloride and Quaternary Ammonium Salt Promoted Baylis-Hillman Reaction. J. Org. Chem. 2001, 66, (2), 406-411.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H331-H335-H336-H351

Causes severe skin burns and eye damage. Toxic if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer.

Precautionary Statements: P201-P202-P260-P264b-P271-P281-P284-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. Wear respiratory protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2827.39
TSCA
Yes

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