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Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines
Min Shi.; Jian-Kang Jiang.; Yan-Shu Feng. Titanium(IV) Chloride and the Amine-Promoted Baylis-Hillman Reaction. Org. Lett. 2000, 16, (2), 2397-2400.
Min Shi.; Yan-Shu Feng. Titanium(IV) Chloride and Quaternary Ammonium Salt Promoted Baylis-Hillman Reaction. J. Org. Chem. 2001, 66, (2), 406-411.
Hazard Statements: H302-H314-H318-H351
Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer.
Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.