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7550-45-0 - Titanium(IV) chloride, 1M soln. in dichloromethane - Titanium tetrachloride - Titanic chloride - H31830 - Alfa Aesar

H31830 Titanium(IV) chloride, 1M soln. in dichloromethane

CAS Number
7550-45-0
Synonyms
Titanium tetrachloride
Titanic chloride

Size Price ($) Quantity Availability
100ml 50.80
500ml 79.60
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Titanium(IV) chloride, 1M soln. in dichloromethane

MDL
MFCD00011267

Chemical Properties

Formula
Cl4Ti
Formula Weight
189.69
Density
1.365
Sensitivity
Moisture Sensitive
Solubility
Reacts with water.

Applications

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines

Notes

Moisture Sensitive. Keep container tightly closed. Store in cool, dry conditions in well sealed containers

Literature References

Min Shi.; Jian-Kang Jiang.; Yan-Shu Feng. Titanium(IV) Chloride and the Amine-Promoted Baylis-Hillman Reaction. Org. Lett. 2000, 16, (2), 2397-2400.

Min Shi.; Yan-Shu Feng. Titanium(IV) Chloride and Quaternary Ammonium Salt Promoted Baylis-Hillman Reaction. J. Org. Chem. 2001, 66, (2), 406-411.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H351

Causes severe skin burns and eye damage. Suspected of causing cancer.

Precautionary Statements: P260-P201-P280-P281-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2827.39
TSCA
Yes

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