H31853 Tris(2-dimethylaminoethyl)amine, 99+%

CAS Number

33527-91-2

Synonyms

Me6TREN

SDS Certificate of Analysis Product Specification Technical Inquiry

Stock No.	Size	Price ($)	Quantity	Availability
H31853-06	5g	128.00
H31853-14	25g	424.00

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Tris(2-dimethylaminoethyl)amine, 99+%

MDL

MFCD00015607

Chemical Properties

Formula

C₁₂H₃₀N₄

Formula Weight

230.40

Boiling Point

70-71°/0.5mm

Refractive Index

1.4540

Storage & Sensitivity

Hygroscopic. Air Sensitive. Store under Nitrogen. Ambient temperatures.

Solubility

Miscible with water.

Applications

Tris(2-dimethylaminoethyl)amine is used as an atom transfer radical polymerization (ATRP) ligand for the creation of telechelic polymers. It is a tripodal polyamine ligand and forms complexes with group 1 metals, which is used in alkali-metal-mediated synthetic applications. Further, it is involved in the macrocyclization processes by reacting with tripodal esters in methanol to give tricyclic cryptands.

Notes

Hygroscopic. Air sensitive. Incompatible with oxidizing agents, acids.

Literature References

Samanta, S. R.; Cai, R.; Percec, V. A rational approach to activated polyacrylates and polymethacrylates by using a combination of model reactions and SET-LRP of hexafluoroisopropyl acrylate and methacrylate. Polym. Chem. 2015, 6 (17), 3259-3270.

Citek, C.; Herres-Pawlis, S.; Stack, T. D. P. Low Temperature Syntheses and Reactivity of Cu₂O₂ Active-Site Models. Acc. Chem. Res. 2015, 48 (8), 2424-2433.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant