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Sulfuryl chloride is often used as a source of chlorine. is widely used as a reagent in the conversion of C-H ? C-Cl adjacent to activating substituent such as carbonyls and sulfoxides. It also chlorinates alkanes, alkenes, alkynes, aromatics, ethers (such as tetrahydrofuran) and epoxides.
Joo-Hack Youn.; Rudolf Herrmann. A simple and efficient preparation of sulfinyl chlorides from disulfides and sulfuryl chloride.Tetrahedron Lett. 1986, 27 (13), 1493-1494 .
Hazard Statements: H314-H331-H335-H336-H350
Causes severe skin burns and eye damage. Toxic if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness. May cause cancer.
Precautionary Statements: P201-P202-P260-P264b-P271-P281-P284-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. Wear respiratory protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant