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7790-99-0 - Iodine monochloride, 1M soln. in dichloromethane - H31938 - Alfa Aesar

H31938 Iodine monochloride, 1M soln. in dichloromethane

CAS Number
7790-99-0
Synonyms

Size Price ($) Quantity Availability
100ml 52.74
500ml 125.60
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Iodine monochloride, 1M soln. in dichloromethane

MDL
MFCD00011354
EINECS
232-236-7

Chemical Properties

Formula
ClI
Formula Weight
162.36
Density
1.420
Sensitivity
Air & Light Sensitive
Solubility
Insoluble in water.

Applications

Iodine monochloride is a useful reagent in organic synthesis and source of I+. It is used as a source of electrophilic iodine in the synthesis of certain aromatic iodides. It also cleaves C-Si bonds. Iodine monochloride will also add to the double bond in alkenes to give chloro-iodo alkanes. It can be dissolved in acetic acid to make Wijs solution.

Notes

Air and light sensitive. Store in cool dry place. Keep away from oxidizing agents.

Literature References

Fred Wudl.; M. Kobayashi.; A. J. Heeger. Poly(isothianaphthene).J. Org. Chem. 1984, 49 (18),3382-3384 .

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H351-H303

Causes severe skin burns and eye damage. Suspected of causing cancer. May be harmful if swallowed.

Precautionary Statements: P260-P201-P280-P281-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2812.10
TSCA
Yes

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