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910251-11-5 - Potassium methoxymethyltrifluoroborate, 95% - H32674 - Alfa Aesar

H32674 Potassium methoxymethyltrifluoroborate, 95%

CAS Number
910251-11-5
Synonyms

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Potassium methoxymethyltrifluoroborate, 95%

MDL
MFCD10566517

Chemical Properties

Formula
C2H5BF3KO
Formula Weight
151.97

Applications

Potassium methoxymethyltrifluoroborate is used in the cross-coupling of mesylated phenol derivatives. The corresponding aryl- and heteroaryl alkoxymethyl compounds are prepared with both electron-rich and electron-poor substituents on the activated alcohol.

Notes

Incompatible with oxidizing agents.

Literature References

O’Brien, N. J.; Brzozowski, M.; Wilson, D. J.; Deady, L. W.; Abbott, B. M. Synthesis and biological evaluation of substituted 3-anilino-quinolin-2(1H)-ones as PDK1 inhibitors. Bioorg. Med. Chem. 2014, 22 (14), 3781-3790.

Molander, G. A.; Beaumard, F. Cross-Coupling of Mesylated Phenol Derivatives with Potassium Alkoxymethyltrifluoroborates. Org. Lett. 2011, 13 (15), 3948-3951.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P260-P201-P280g-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2931.90
TSCA
No

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