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10294-34-5 - Boron trichloride, 1M soln. in hexanes, mixed isomers - H32833 - Alfa Aesar

H32833 Boron trichloride, 1M soln. in hexanes, mixed isomers

CAS Number
10294-34-5
Synonyms

Size Price ($) Quantity Availability
100ml 71.80
500ml 230.00
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Boron trichloride, 1M soln. in hexanes, mixed isomers

MDL
MFCD00011313
EINECS
233-658-4

Chemical Properties

Formula
BCl3
Formula Weight
117.17
Density
0.738
Sensitivity
Moisture Sensitive
Solubility
Reacts with water.

Applications

A mild, selective combination reagent for the cleavage of primary alkyl aryl ethers. Boron trichloride is a selective demethylating agent. For preparing methyl esters of fatty acids and for transesterification of triglycerides. Mainly used as semiconductor silicon doping source or organic synthesis catalyst, also used for making high purity boron or organic boron.

Notes

Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture, heat. Unstable. Store at 2-8°C.

Literature References

F.M. Dean,; J.Goodchild,; L.E. Houghton,; J.A. Martin,; R.B. Morton,; B. Parton,; A.W. Price, ;Nongyow Somvichien. Boron trichloride as a selective demethylating agent. Tetrahedron Letters. 1996, 7(35),4153-4159.

N. N. Greenwood,; K. Wade .Complexes of boron trichloride with pyridine and piperidine. J. Chem. Soc., year of publication , 1130-1141.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H300-H331-H314-H318-H361-H336-H373-H304

Highly flammable liquid and vapour. Fatal if swallowed. Toxic if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of damaging fertility or the unborn child. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways.

Precautionary Statements: P210-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2812.90
TSCA
Yes

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