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H32962 Zinc chloride, 0.7M soln. in THF

CAS Number
7646-85-7
Synonyms

Stock No. Size Price ($) Quantity Availability
H32962-AE 100ml 95.80
H32962-AP 500ml 239.00
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Zinc chloride, 0.7M soln. in THF

MDL
MFCD00011295
EINECS
231-592-0

Chemical Properties

Formula
Cl2Zn
Formula Weight
136.29
Density
0.948
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water (4320 mg/ml at 25°C), ethanol (slightly), acetone (slightly), ether, and glycerol.

Applications

Zinc chloride is a widely used as a moderate-strength Lewis acid. In biochemistry research this is used for a source of the zinc ion. It is also be used alone or with phenols for preserving railway ties, fireproofing timber, and with ammonium chloride as a flux for soldering and etching of metals. Zinc chloride is used in the synthesis of the ferrocenylarenes. It is used for the in situ generation of organozincate reagents by reacting with Grignard compounds and also to catalyze chloromethylation of resins for solid phase peptide synthesis.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents. It is sensitive to moisture. Store under dry inert gas. Protect from humidity and water.

Literature References

P. Shanthan Rao.; R.V. Venkataratnam. Zinc chloride as a new catalyst for knoevenagel condensation. Tetrahedron Letters. 1991, 32 (41), 5821-5822.

Sophie Peulon.; Daniel Lincot. Mechanistic Study of Cathodic Electrodeposition of Zinc Oxide and Zinc Hydroxychloride Films from Oxygenated Aqueous Zinc Chloride Solutions. J. Electrochem. Soc. 1998, 145 (3), 864-874.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H314-H335-H336-H351

Highly flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer.

Precautionary Statements: P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2827.39
TSCA
Yes

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