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7646-85-7 - Zinc chloride, 0.7M soln. in THF - H32962 - Alfa Aesar

H32962 Zinc chloride, 0.7M soln. in THF

CAS Number
7646-85-7
Synonyms

Size Price ($) Quantity Availability
100ml 93.40
500ml 234.00
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Zinc chloride, 0.7M soln. in THF

MDL
MFCD00011295
EINECS
231-592-0

Chemical Properties

Formula
Cl2Zn
Formula Weight
136.29
Density
0.948
Solubility
Soluble in water (4320 mg/ml at 25°C), ethanol (slightly), acetone (slightly), ether, and glycerol.

Applications

Zinc chloride is a widely used as a moderate-strength Lewis acid. In biochemistry research this is used for a source of the zinc ion. It is also be used alone or with phenols for preserving railway ties, fireproofing timber, and with ammonium chloride as a flux for soldering and etching of metals. Zinc chloride is used in the synthesis of the ferrocenylarenes. It is used for the in situ generation of organozincate reagents by reacting with Grignard compounds and also to catalyze chloromethylation of resins for solid phase peptide synthesis.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents. It is sensitive to moisture. Store under dry inert gas. Protect from humidity and water.

Literature References

P. Shanthan Rao.; R.V. Venkataratnam. Zinc chloride as a new catalyst for knoevenagel condensation. Tetrahedron Letters. 1991, 32 (41), 5821-5822.

Sophie Peulon.; Daniel Lincot. Mechanistic Study of Cathodic Electrodeposition of Zinc Oxide and Zinc Hydroxychloride Films from Oxygenated Aqueous Zinc Chloride Solutions. J. Electrochem. Soc. 1998, 145 (3), 864-874.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2827.39
TSCA
Yes

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