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For preparing perfluoro-aromatic nitrogen heterocyclic compounds from their perchloro-analogues by exchange with potassium fluoride in the absence of solvent has been extended to the pyridazine system. Tetrafluoropyridazine readily undergoes nucleophilic substitution. Ultrathin plasma polymer films is prepared from tetrafluoropyridazine. The variation in the orientation of products formed with the olefin used in polyfluoroalkylations with tetrafluoropyridazine is discussed.
Wojciech Dmowski,; Alois Haas. Trifluoromethanethiolate ion. Part 3. Reactions with tetrafluoropyridazine and tetrafluoropyrimidine . J. Chem. Soc., Perkin Trans. . 1988, 1(5),1179-1181.
R. D. Chambers,; J. A. H. MacBride,; W. K. R. Musgrave. Polyfluoro-heterocyclic compounds. Part XII. Preparation and nucleophilic substitution of tetrafluoropyridazine. J. Chem. Soc. C,. 1968, 2116-2119.
Hazard Statements: H301-H315-H319-H335
Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.