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H33861 Isopropylboronic acid pinacol ester, 98%

CAS Number
76347-13-2
Synonyms
2-Isopropyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Stock No. Size Price ($) Quantity Availability
H33861-03 1g 19.40
H33861-06 5g 59.60
H33861-14 25g 235.00
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Isopropylboronic acid pinacol ester, 98%

MDL
MFCD05663856

Chemical Properties

Formula
C9H19BO2
Formula Weight
170.06
Boiling Point
115°/60mm
Refractive Index
1.4090
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly soluble in water.

Applications

Isopropylboronic acid pinacol ester is used as pharmaceutical intermediate.

Notes

Store in a cool, dry place, in a well sealed container. Store away from oxidizing agents.

Literature References

Tim G. Elford; Stefan Nave; Ravindra P. Sonawane and Varinder K. Aggarwal. Total Synthesis of (+)-Erogorgiaene Using Lithiation-Borylation Methodology, and Stereoselective Synthesis of Each of Its Diastereoisomers. J. Am. Chem. Soc. 2011, 133 (42), 16798-16801.

Dr. Benjamin M. Partridge; Dr. Laëtitia Chausset-Boissarie; Matthew Burns; Alexander P. Pulis; Prof. Varinder K. Aggarwal. Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates. Angewandte Chemie International Edition. 2010, 51 (47), 11795-11799.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2934.99
TSCA
No

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