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14077-58-8 - 2-Ethoxyacetyl chloride, 97%, stab. with 0.3% Magnesium oxide - H34443 - Alfa Aesar

H34443 2-Ethoxyacetyl chloride, 97%, stab. with 0.3% Magnesium oxide

CAS Number
14077-58-8
Synonyms

Size Price ($) Quantity Availability
5g 50.47
25g 186.43
100g 420.80
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2-Ethoxyacetyl chloride, 97%, stab. with 0.3% Magnesium oxide

MDL
MFCD11170566
EINECS
237-930-3

Chemical Properties

Formula
C4H7ClO2
Formula Weight
122.55
Solubility
Insoluble in water.

Applications

It is employed in fine chemical syntheses and used as pharmaceutical intermediates. A trace of cis-ethoxyacetamide was also detected and isolated with an authentic sample prepared from the reaction of cis-3-amino-6-methylchroman-4-01 (2) with 2-ethoxyacetyl chloride.

Notes

Reacts with strong oxidizing agents. Store at room temperature.

Literature References

Karen K. Bach.; Hesham R. El-Seedi.; Henrik M. Jensen.; Helene B. Nielsen.; Ib Thomsen.; Kurt B.G. Torssell. 1,3-Dipolar cycloadditions of ethoxycarbonyl-nitrile benzylimine, EtOOC C ? Full-size image (<1 K) - Full-size image (<1 K) CH2C6H5, and synthesis of β-amino acids. Synthesis and reactions of ethyl 2-chloro-2-ethoxyacetate and 2-chloro-2-ethoxyacetyl chloride. Tetrahedron. 1994, 50 (25),7543-7556.

Gordon W. Rewcastle.; Hamish S. Sutherland.; Claudette A. Weir.; Adrian G. Blackburn.; William A. Denny. An improved synthesis of isonitrosoacetanilides. Tetrahedron Lett. 2005, 46 (50),8719-8721.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H226-H332

Causes severe skin burns and eye damage. Flammable liquid and vapour. Harmful if inhaled.

Precautionary Statements: P210-P260-P261-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2918.99
TSCA
No

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