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H34453 6-Bromoimidazo[1,2-a]pyridine, 98%

CAS Number
6188-23-4
Synonyms

Stock No. Size Price ($) Quantity Availability
H34453-03 1g 69.80
H34453-06 5g 228.00
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6-Bromoimidazo[1,2-a]pyridine, 98%

MDL
MFCD06496200

Chemical Properties

Formula
C7H5BrN2
Formula Weight
197.03
Melting point
78-80°
Storage & Sensitivity
Ambient temperatures.
Solubility
slightly soluble in water.

Applications

It is used in organic syntheses and as pharmaceutical intermediates. The best results were obtained with lactams that could be introduced on the 6-bromoimidazo[1,2-a]pyridine. 1,2-dihydro-5-imidazo [1,2-a]pyridin-6-yl-6-methyl-2-oxo-3-pyridinecarbonitrile hydrochloride monohydrate 6 was synthesized in 5 steps from 6-bromoimidazo[1,2-a] pyridine using [2- 14 C] cyanoacetamide as the source of the radiolabel.

Notes

Incompatible with strong oxidizing agents. Store at room temperature.

Literature References

Jamal Koubachi.; Saïd El Kazzouli.; Sabine Berteina-Raboin.; Abderrahim Mouaddib.; Gérald Guillaumet. Synthesis of Polysubstituted Imidazo[1,2-a]pyridines via Microwave-Assisted One-Pot Cyclization/Suzuki Coupling/Palladium-Catalyzed Heteroarylation.J. Org. Chem. 2007, 72 (20),7650-7655.

Giuseppe Trapani.; Massimo Franco.; Laura Ricciardi .; Andrea Latrofa.; Giuseppe Genchi.; Enrico Sanna.; Francesca Tuveri.; Elisabetta Cagetti.; Giovanni Biggio.; Gaetano Liso. Synthesis and Binding Affinity of 2-Phenylimidazo[1,2-a]pyridine Derivatives for both Central and Peripheral Benzodiazepine Receptors. A New Series of High-Affinity and Selective Ligands for the Peripheral Type. J. Med. Chem. 1997, 40 (19),3109-3118.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2933.99
TSCA
No

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