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234111-08-1 - 2-Bromo-6-iodopyridine, 97% - H34478 - Alfa Aesar

H34478 2-Bromo-6-iodopyridine, 97%

CAS Number
234111-08-1
Synonyms

Size Price ($) Quantity Availability
250mg 62.40
1g 173.00
5g 577.00
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2-Bromo-6-iodopyridine, 97%

MDL
MFCD08059557

Chemical Properties

Formula
C5H3BrIN
Formula Weight
283.89
Melting point
139-143°
Sensitivity
Light Sensitive

Applications

6-trifluoromethyl-2-pyridinecarboxylic acid (4; 87%) was obtained from 2-bromo-6-(trifluoromethyl)pyridine, which was in turn derived from 2-bromo-6-iodopyridine by trifluoromethylating displacement of iodine.

Notes

Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Fabrice Cottet, Marc Marull1, Olivier Lefebvre1 andManfred Schlosser.Recommendable Routes to Trifluoromethyl-Substituted Pyridine- and Quinolinecarboxylic Acids. European Journal of Organic Chemistry. 2003, 8 1559-1568.

Tatsushi Imahori,; Masanobu Uchiyama,; Takao Sakamoto,; Yoshinori Kondo. Regiocontrolled deprotonative-zincation of bromopyridines using aminozincates. Chem. Commun., 2001, (23), 2450-2451.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2933.39
TSCA
No

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