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Reduction of pentafluoroaniline (PFA) leads to rapid fluoride elimination to form the aminotetrafluorophenyl radical. Homolytic reactions of perfluoroaromatic compounds(Formation of pentafluorophenyl radicals from pentafluoroaniline, and their reactions with aromatic compounds).
R. N. Haszeldine,; F. Nyman . Perfluoroalkyl derivatives of sulphur. Part V. αα-Difluoro-α-(trifluorothio)acetic acid. J. Chem. Soc., 1956, 2684-2689.
Robert J. Willenbring,; Javid Mohtasham,; R. Winter, Gary L. Gard.New pentafluorothio(SF5) alkylsulfonic acids. Canadian Journal of Chemistry. 1989, 67(11), 2037-2040.
Hazard Statements: H302+H312+H332-H315-H319-H335
Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c
Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant