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H51065 1-Aza-18-crown-6, 95%

CAS Number
33941-15-0
Synonyms
1,4,7,10,16-Pentaoxa-13-azacyclooctadecane

Stock No. Size Price ($) Quantity Availability
H51065-MD 250mg 59.80
H51065-03 1g 177.00
H51065-06 5g 716.00
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1-Aza-18-crown-6, 95%

MDL
MFCD00075466
EINECS
251-751-8

Chemical Properties

Formula
C12H25NO5
Formula Weight
263.33
Melting point
46-49°
Storage & Sensitivity
Air Sensitive. Store under Argon. Ambient temperatures.
Solubility
Insoluble in water.

Applications

1-Aza-18-crown-6 is used as building block for the synthesis of bis-crown ethers, lariat ethers and other monofunctionalized macrocycles. It is also used as pharmaceutical intermediate.

Notes

Air sensitive. Store away from oxidizing agents.

Literature References

Kamaluddin Abdur-Rashid; Dmitry G.Gusev; Alan J.Lough; Robert H.Morris. Intermolecular proton-hydride bonding in ion pairs:? Synthesis and structural properties of [K(Q)][MH5(PiPr3)2] (M = Os, Ru; Q = 18-crown-6, 1-aza-18-crown-6, 1,10-diaza-18-crown-6). Organometallics. 2000, 19, (5),834-843

 

Huimin Luo; Sheng Dai; Peter V.Bonnesen. Solvent extraction of Sr2+ and Cs+ based on room-temperature ionic liquids containing monoaza-substituted crown ethers. Anal. Chem. 2004, 76, (10),2773-2779

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H332-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1074079
Harmonized Tariff Code
2934.99
TSCA
No

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