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H51090 2-(Tri-n-butylstannyl)thiazole, 96%

CAS Number
121359-48-6
Synonyms
Tri-n-butyl-2-thiazolyltin

Stock No. Size Price ($) Quantity Availability
H51090-03 1g 121.00
H51090-06 5g 500.00
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2-(Tri-n-butylstannyl)thiazole, 96%

MDL
MFCD01319057

Chemical Properties

Formula
C15H29NSSn
Formula Weight
374.17
Boiling Point
307-309°
Density
1.19
Storage & Sensitivity
Ambient temperatures.
Solubility
Not miscible or difficult to mix.

Applications

Used as reagent for arylation of thiazole by Stille cross-coupling.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Rüdiger Wittenberg; Jiri Srogl; Masahiro Egi; and Lanny S. Liebeskind. Ketone Synthesis under Neutral Conditions. Cu(I) Diphenylphosphinate-Mediated, Palladium-Catalyzed Coupling of Thiol Esters and Organostannanes. Org. Lett,. 2003, 5(17), 3033-3035.

Hao Li; Hao Yang; and Lanny S. Liebeskind. Synthesis of High Enantiopurity N-Protected α-Amino Ketones by Thiol Ester-Organostannane Cross-Coupling Using pH-Neutral Conditions. Org. Lett., 2008, 10(19), 4375-4378.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H312-H315-H319-H372

Toxic if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P264b-P270-P280-P301+P310-P302+P352-P305+P351+P338-P312-P314-P330-P332+P313-P362-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Get medical advice/attention if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2934.10
TSCA
No

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