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121359-48-6 - 2-(Tri-n-butylstannyl)thiazole, 96% - Tri-n-butyl-2-thiazolyltin - H51090 - Alfa Aesar

H51090 2-(Tri-n-butylstannyl)thiazole, 96%

CAS Number
121359-48-6
Synonyms
Tri-n-butyl-2-thiazolyltin

Size Price ($) Quantity Availability
1g 117.00
5g 490.00
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2-(Tri-n-butylstannyl)thiazole, 96%

MDL
MFCD01319057

Chemical Properties

Formula
C15H29NSSn
Formula Weight
374.17
Boiling Point
307-309°
Density
1.19
Solubility
Not miscible or difficult to mix.

Applications

Used as reagent for arylation of thiazole by Stille cross-coupling.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

Rüdiger Wittenberg; Jiri Srogl; Masahiro Egi; and Lanny S. Liebeskind. Ketone Synthesis under Neutral Conditions. Cu(I) Diphenylphosphinate-Mediated, Palladium-Catalyzed Coupling of Thiol Esters and Organostannanes. Org. Lett,. 2003, 5(17), 3033-3035.

Hao Li; Hao Yang; and Lanny S. Liebeskind. Synthesis of High Enantiopurity N-Protected α-Amino Ketones by Thiol Ester-Organostannane Cross-Coupling Using pH-Neutral Conditions. Org. Lett., 2008, 10(19), 4375-4378.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H312-H315-H319-H372-H400-H410

Toxic if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Causes damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

Precautionary Statements: P273-P280-P309-P310-P501a

Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2934.10
TSCA
No

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