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1068-55-9 - Isopropylmagnesium chloride, 1M in MeTHF - H51155 - Alfa Aesar

H51155 Isopropylmagnesium chloride, 1M in MeTHF

CAS Number
1068-55-9
Synonyms

Size Price ($) Quantity Availability
100ml 41.30
500ml 133.00
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Isopropylmagnesium chloride, 1M in MeTHF

MDL
MFCD00000466

Chemical Properties

Formula
C3H7ClMg
Formula Weight
102.85
Sensitivity
Air & Moisture Sensitive
Solubility
It reacts violently with water.

Applications

Isopropyl magnesium chloride is used primarily to add an iso-propyl group to carbonyl groups. This reagent can also be used as a strong base in aprotic solvents.

Notes

Air & moisture sensitive. Incompatible with oxidizing agents and bases.

Literature References

Shimpei Sugiyama; Hitomi Shimizu; Tsuyoshi Satoh. The first example of γ-chloromagnesio γ-lactones: their generation from γ-tolylsulfinyl γ-lactones with isopropylmagnesium chloride, stability, and reaction with electrophiles. Tetrahedron Letters. 2006, 47, (49),8771-8775

 

Juan de M.Munoz; Jesus Alcazar; Antonio de la Hoz; Angel Diaz-Ortiz; Sergio-A. Alonso de Diego. Preparation of amides mediated by isopropylmagnesium chloride under continuous flow conditions. Green Chem. 2012, 14, (5),1335-1341

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H314-H318

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

Recommended

  • A10173

    Trifluoromethanesulfonic acid, 98+%
  • A10312

    N-Hydroxysuccinimide, 98+%
  • H51156

    Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF
  • 10515

    Lithium chloride, anhydrous, 99%
  • H54840

    Isopropylmagnesium bromide, 3M in 2-MeTHF

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