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807329-97-1 - Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF - H51156 - Alfa Aesar

H51156 Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF

CAS Number
807329-97-1
Synonyms

Size Price ($) Quantity Availability
100ml 86.20
500ml 358.00
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Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF

MDL
MFCD07784514

Chemical Properties

Formula
C3H7ClMg.LiCl
Formula Weight
145.24
Flash Point
-17°(1.4°F)
Density
0.951
Sensitivity
Air & Moisture Sensitive
Solubility
Miscible with ethers and amines.

Applications

Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.

Notes

Air and moisture sensitive. Incompatible with oxidizing agents and water.

Literature References

Huddleston, N. E.; Roy, A.; Bilbrey, J. A.; Zhao, Y.; Locklin, J. Functionalization of Reactive End Groups in Surface-Initiated Kumada Catalyst-Transfer Polycondensation. Macromol. Symp. 2015, 351 (1), 27-36.

Hickey, M. J.; Kingston, L. P.; Allen, P. H.; Johnson, T.; Wilkinson, D. J. A short expedient synthesis of [14C]Ticlopidine. J. Labelled Compd. Radiopharm. 2014, 57 (3), 172-174.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H314-H318

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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