I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.
Phenylmagnesium chloride is used primarily to add an iso-propyl group to carbonyl groups. This reagent can also be used as a strong base in aprotic solvents. It is also used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).
Bogdan Boduszek; Henry J.Shine; T.Krishnan Venkatachalam. Reactions of phenylmagnesium chloride and phenyllithium with thianthrene cation radical perchlorate. Evidence for electron transfer: formation and decomposition of 5-substituted thianthreniumyl perchlorates. J. Org. Chem. 1989, 54, (7),1616-1626
Henry Gilman; Nina B. St. John. The preparation of phenylmagnesium chloride. Recueil des Travaux Chimiques des Pays-Bas. 1930, 49, (8),717-723
Hazard Statements: H225-H261-H302-H312-H333-H314-H318
Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. Harmful in contact with skin. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.