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100-59-4 - Phenylmagnesium chloride, 1M in MeTHF - H51157 - Alfa Aesar

H51157 Phenylmagnesium chloride, 1M in MeTHF

CAS Number
100-59-4
Synonyms

Size Price ($) Quantity Availability
100ml 33.70
500ml 141.00
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Phenylmagnesium chloride, 1M in MeTHF

MDL
MFCD00000464

Chemical Properties

Formula
C6H5MgCl
Formula Weight
136.86
Flash Point
-17°(1.4°F)
Sensitivity
Air & Moisture Sensitive
Solubility
It reacts violently with water.

Applications

Phenylmagnesium chloride is used primarily to add an iso-propyl group to carbonyl groups. This reagent can also be used as a strong base in aprotic solvents. It is also used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

Notes

Air & moisture sensitive. Incompatible with heat.

Literature References

Bogdan Boduszek; Henry J.Shine; T.Krishnan Venkatachalam. Reactions of phenylmagnesium chloride and phenyllithium with thianthrene cation radical perchlorate. Evidence for electron transfer: formation and decomposition of 5-substituted thianthreniumyl perchlorates. J. Org. Chem. 1989, 54, (7),1616-1626

 

Henry Gilman; Nina B. St. John. The preparation of phenylmagnesium chloride. Recueil des Travaux Chimiques des Pays-Bas. 1930, 49, (8),717-723

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H314-H302-H312-H333

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Harmful if swallowed. Harmful in contact with skin. May be harmful if inhaled.

Precautionary Statements: P210-P231+P232-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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