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H51157 Phenylmagnesium chloride, 1M in MeTHF

CAS Number
100-59-4
Synonyms

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Bulk/Specialty

Phenylmagnesium chloride, 1M in MeTHF

MDL
MFCD00000464

Chemical Properties

Formula
C6H5MgCl
Formula Weight
136.86
Flash Point
-17°(1.4°F)
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Ambient temperatures.
Solubility
It reacts violently with water.

Applications

Phenylmagnesium chloride is used primarily to add an iso-propyl group to carbonyl groups. This reagent can also be used as a strong base in aprotic solvents. It is also used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

Notes

Air & moisture sensitive. Incompatible with heat.

Literature References

Bogdan Boduszek; Henry J.Shine; T.Krishnan Venkatachalam. Reactions of phenylmagnesium chloride and phenyllithium with thianthrene cation radical perchlorate. Evidence for electron transfer: formation and decomposition of 5-substituted thianthreniumyl perchlorates. J. Org. Chem. 1989, 54, (7),1616-1626

 

Henry Gilman; Nina B. St. John. The preparation of phenylmagnesium chloride. Recueil des Travaux Chimiques des Pays-Bas. 1930, 49, (8),717-723

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H314-H335

Highly flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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