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23719-80-4 - Cyclopropylmagnesium bromide, 0.5M in MeTHF - H51158 - Alfa Aesar

H51158 Cyclopropylmagnesium bromide, 0.5M in MeTHF

CAS Number

Size Price ($) Quantity Availability
50ml 142.00
100ml 224.00
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Cyclopropylmagnesium bromide, 0.5M in MeTHF


Chemical Properties

Formula Weight
Air & Moisture Sensitive
Reacts with water.


Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).


Air and Moisture Sensitive, store away from air and water/moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

H. M. Walborsky; Christoph Zimmermann. The surface nature of Grignard reagent formation.J. Am. Chem. Soc.,1992, 114(13), 4996-5000.

Chutian Shu; Kanwar Sidhu; Li Zhang; Xiao-jun Wang; Dhileepkumar Krishnamurthy; and Chris H. Senanayake. Palladium-Catalyzed Cross-Coupling of Cyclopropylmagnesium Bromide with Aryl Bromides Mediated by Zinc Halide Additives. J. Org. Chem., 2010, 75(19), 6677-6680.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H260-H313-H314-H318

Highly flammable liquid and vapour. In contact with water releases flammable gases which may ignite spontaneously. May be harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P223-P210-P231+P232-P260u-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
Packing Group
Harmonized Tariff Code


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