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23719-80-4 - Cyclopropylmagnesium bromide, 0.5M in MeTHF - H51158 - Alfa Aesar

H51158 Cyclopropylmagnesium bromide, 0.5M in MeTHF

CAS Number
23719-80-4
Synonyms

Size Price ($) Quantity Availability
50ml 135.13
100ml 202.00
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Cyclopropylmagnesium bromide, 0.5M in MeTHF

MDL
MFCD00672094

Chemical Properties

Formula
C3H5BrMg
Formula Weight
145.28
Sensitivity
Air & Moisture Sensitive
Solubility
Reacts with water.

Applications

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

Notes

Air and Moisture Sensitive, store away from air and water/moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literature References

H. M. Walborsky; Christoph Zimmermann. The surface nature of Grignard reagent formation.J. Am. Chem. Soc.,1992, 114(13), 4996-5000.

Chutian Shu; Kanwar Sidhu; Li Zhang; Xiao-jun Wang; Dhileepkumar Krishnamurthy; and Chris H. Senanayake. Palladium-Catalyzed Cross-Coupling of Cyclopropylmagnesium Bromide with Aryl Bromides Mediated by Zinc Halide Additives. J. Org. Chem., 2010, 75(19), 6677-6680.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H261-H314-H318

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P231+P232-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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